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Scotchban Protector Page
3M Canada Company
Post Office Box 5757
London, Ontario N6A 4T1
Medical Emergency Telephone: (519)451-2500, Ext. 2222
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Material Safety Data Sheet
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Document id : 07-8773-9 Issue date : 12/05/2001
Version : 9.00 Supersedes date : 12/07/1999
Prepared by: Environmental Health and Safety Services Department, 3M
Canada Company.
Telephone: (519) 452-6102, Fax: (519) 452-6015.
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1 Product Identification
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Tradename:
FC-829A SCOTCHBAN(TM) PROTECTOR (OBSOLETE)
Product ID:
98-0211-9269-9 98-0211-9270-7 98-0211-9271-5 98-0211-9272-3
Intended Use of Product:
Protector
Division:
3M SPECIALTY MATERIALS
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2 Composition/Information on Ingredients
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Ingredient Name CAS Number Percentage
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WATER 7732-18-5 60 - 64
COPOLYMERIC FLUOROALIPHATIC ESTER Trade Secret 28 - 32
POLYETHYLENE GLYCOL 25322-68-3 7
RESIDUAL ORGANIC FLUOROCHEMICALS Mixture < 2
ETHYL ACETATE 141-78-6 1
NOTE:
COPOLYMERIC FLUOROALIPHATIC ESTER is a non-hazardous Trade Secret
material according to WHMIS criteria.
RESIDUAL ORGANIC FLUOROCHEMICALS has no CAS number.
FC-829A SCOTCHBAN(TM) PROTECTOR (OBSOLETE) Page 2 of 8
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3 Hazards Identification
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Critical Hazards
No data available.
See Sections 7 and 11 for further information.
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4 First Aid Measures
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Instructions for Eye Contact:
Immediately flush eyes with large amounts of water. Get immediate
medical attention.
Instructions for Skin Contact:
Flush skin with large amounts of water. If irritation persists, get
medical attention.
Instructions for Inhalation:
If signs/symptoms occur, remove person to fresh air. If
signs/symptoms continue, call a physician.
Instructions for Ingestion:
If swallowed, call a physician immediately. Only induce vomiting at
the instruction of a physician. Never give anything by mouth to an
unconscious person.
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5 Fire Fighting Measures
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Flash point: None (Setaflash CC)
Lower Explosive Limit (%): Not applicable
Upper Explosive Limit (%): Not applicable
Autoignition temperature: Not applicable
Suitable Extinguishing Media:
Water; Carbon Dioxide; Dry chemical; Foam;
Exposure Hazards during Fire:
No data available.
Combustion Products from Fire:
Carbon monoxide and carbon dioxide; hydrogen fluoride; Toxic
vapours, gases or particulates;
Fire Fighting Procedures:
Wear full protective clothing, including helmet, self-contained,
positive pressure or pressure demand breathing apparatus, bunker
coat and pants, bands around arms, waist and legs, face mask, and
protective covering for exposed areas of the head.
FC-829A SCOTCHBAN(TM) PROTECTOR (OBSOLETE) Page 3 of 8
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6 Accidental Release Measures
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Personal Precautions:
Observe precautions from other sections.
Spill Response:
Ventilate area. Contain spill. Cover with absorbent material.
Collect spilled material. Clean up residue. Place in a closed
container.
Methods for Disposal:
Incinerate in an industrial or commercial facility in the presence
of a combustible material. Combustion products will include HF.
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7 Handling and Storage
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Storage Requirements:
Store away from areas where product may come into contact with food
or pharmaceuticals. Store at temperatures below 120 degrees F (49
degrees C). Store at temperatures above 32 degrees F (O degrees C).
Keep container dry. Keep container closed when not in use.
Incompatible Materials:
Store out of direct sunlight.
Ventilation:
Keep container in well-ventilated area.
Explosion Prevention:
Nonflammable.
Use Instructions:
Allow material to return to room temperature before use. Keep
container tightly closed. No smoking: Smoking while using this
product can result in contamination of the tobacco and/or smoke and
lead to the formation of the hazardous decomposition products
mentioned in section 10 of this MSDS.
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8 Exposure Controls/Personal Protection
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Personal Protection
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Eye Protection:
Avoid eye contact with vapour, spray, or mist. Wear vented goggles.
Hand Protection:
Wear appropriate gloves when handling this material. A pair of
gloves made from the following material(s) are recommended: butyl
rubber; natural rubber;
FC-829A SCOTCHBAN(TM) PROTECTOR (OBSOLETE) Page 4 of 8
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Skin Protection:
Avoid skin contact.
Respiratory Protection:
Avoid breathing of airborne material. Select one of the following
NIOSH approved respirators based on airborne concentration of
contaminants: half-mask organic vapour respirator with dust/mist
prefilter;
Ingestion (Prevention):
Do not eat, drink or smoke when using this product. Wash exposed
areas thoroughly with soap and water. Wash hands after handling and
before eating.
Recommended Ventilation:
Provide appropriate local exhaust for heat curing. Curing ovens must
be exhausted to outdoors or to a suitable emission control device.
If exhaust ventilation is not adequate, use appropriate respiratory
protection. Provide ventilation adequate to control vapour
concentrations below recommended exposure limits and/or control
spray or mist. Local exhaust ventilation is recommended for spraying
and drying operations.
Ingredient Exposure Data
------------------------
WATER (7732-18-5)
LD50 (rat, oral): > 90 ml/kg
COPOLYMERIC FLUOROALIPHATIC ESTER (Trade Secret)
Specific Ingredient Data: No data available.
POLYETHYLENE GLYCOL (25322-68-3)
LD50 (rat, oral): 600 mg/kg
RESIDUAL ORGANIC FLUOROCHEMICALS (Mixture)
Specific Ingredient Data: No data available.
ETHYL ACETATE (141-78-6)
LD50 (rat, oral): 5600 mg/kg
LC50 (rat, inhalation/4 hours): 19600 ppm
PIN (Product Identification Number): 1173
Ontario TWAEV: 400 ppm 1440 mg/m3
ACGIH TLV-TWA: 400 ppm 1440 mg/m3
Specific Ingredient Data: LD50 (rabbit, dermal): > 18 g/kg
FC-829A SCOTCHBAN(TM) PROTECTOR (OBSOLETE) Page 5 of 8
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9 Physical and Chemical Properties
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Physical form,Color,Odour: viscous liquid; amber; slight
acrylate odour;
Odour Threshold: No data available.
pH: Approximately 4.0
Boiling point/boiling range: Approximately 90 C
Melting point/melting range: Not applicable
Vapour pressure: Approximately 18.2 mmHg at 20 C
Water Solubility: Dispersable
Partition coefficient (K o/w): No data available.
Specific gravity: Approximately 1.1 Water=1
Vapour density: Approximately 0.63 Air=1 at 20
C
Volatile organic compounds: 11 gms/liter at 20 C
Evaporation rate: < 1 BuOAc=1
Viscosity: Not Available.
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10 Stability and Reactivity
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Conditions to Avoid:
None known.
Materials to Avoid:
None known.
Hazardous Decomposition:
Carbon monoxide and carbon dioxide; hydrogen fluoride; Toxic
vapours, gases or particulates;
Stability and Reactivity:
Stable. Hazardous polymerization will not occur.
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11 Toxicological Information
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Effects from Eye Contact:
Mild Eye Irritation: signs/symptoms can include redness, swelling,
pain, and tearing.
Effects from Skin Contact:
Mild Skin Irritation (after prolonged or repeated contact):
signs/symptoms can include redness, swelling, and itching.
Effects from Inhalation:
Single overexposure, above recommended guidelines, may cause:
Irritation (upper respiratory): signs/symptoms can include soreness
of the nose and throat, coughing and sneezing.
Effects from Ingestion:
Animal studies conducted on organic fluorochemicals which may be
present in this product indicate effects including liver
FC-829A SCOTCHBAN(TM) PROTECTOR (OBSOLETE) Page 6 of 8
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disturbances, weight loss, loss of appetite, lethargy, and
neurological, pancreatic, adrenal and hematologic effects. There are
no known human health effects from anticipated exposure to these
organic fluorochemicals when used as intended and instructed.
Sensitization Information:
No data available.
Carcinogenicity:
No data available.
Mutagenicity:
No data available.
Reproductive Effects:
No data available.
Other Effects & Information:
A Product Toxicity Summary Sheet is available. This product may
contain one or more organic fluorochemicals that have the potential
to be absorbed and remain in the body for long periods of time,
either as the parent molecule or as metabolites, and may accumulate
with repeated exposures. There are no known human health effects
from anticipated exposure to these organic fluorochemicals when used
as intended and instructed The presence of organic fluorochemicals
in the blood of the general population and subpopulations, such as
workers, has been published dating back to the 1970's. 3M's
epidemiological study of its own workers indicates no adverse
effects.
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12 Ecological Information
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Persistence/Biodegradability:
This product may contain one or more organic fluorochemicals that
have the potential to resist degradation and persist in the
environment.
Ecotoxicity Data:
No data available.
Other Effects and Information:
Chemical Oxygen Demand (COD): 0.52 g/g
20-Day Biochemical Demand (BOD20): 0.11 g/g
BOD20/COD: 0.2
96 hour LC50, Fathead minnow (Pimephales promelas): > 1000 mg/l
48 hour EC50, (Water flea (Daphnia magna)): > 1000 mg/l
Microtox (Photobacterium phosphoreum) 30-min EC50: > 1000 mg/l
Activated Sludge Respiration Inhibition 3-hr Exposure EC50: > 1000
mg/l
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13 Disposal Considerations
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FC-829A SCOTCHBAN(TM) PROTECTOR (OBSOLETE) Page 7 of 8
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Product as Sold:
No data available.
Product Packaging:
No data available.
Special Instructions:
Since regulations vary, consult applicable regulations or
authorities before disposal.
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14 Transportation Information
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Transportation of Dangerous Goods
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TDG Classification: Non-Regulated Material
International Dangerous Goods Classification
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IMO Class: No data available.
ICAO Class: No data available.
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15 Regulatory Information
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WHMIS Classification: D2B
NOTE:
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations (CPR) and the MSDS
contains all the information required by the CPR.
Product Certifications:
The product on this MSDS, or all its components, is included on the
following countries' chemical inventories, as noted:
AICS - Australian Inventory of Chemical Substances
TSCA - Toxic Substances Control Act (USA)
DSL - Domestic Substances List (Canada)
PICCS - Philippines Inventory of Commercial Chemical Substances
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16 Other Information
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Reason for Reissue:
The following Sections and topics have been updated or revised:
Update Tradename
Section 15 - Regulatory Information: Product Certifications
Copyright, 1997, Minnesota Mining and Manufacturing Company. All
FC-829A SCOTCHBAN(TM) PROTECTOR (OBSOLETE) Page 8 of 8
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rights reserved. Copying and/or downloading of this information for
the purpose of properly utilizing 3M products is allowed provided
that:
1) the information is copied in full with no changes unless prior
written agreement is obtained from 3M, and
2) neither the copy nor the original is resold or otherwise
distributed with the intention of earning a profit thereon.
The information in this Material Safety Data Sheet (MSDS) is
believed to be correct as of the date issued. 3M MAKES NO
WARRANTIES, EXPRESSED OR IMPLIED, STATUTORY OR OTHERWISE, INCLUDING,
BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OR CONDITION OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF
PERFORMANCE OR USAGE OF TRADE. User is responsible for determining
whether the 3M product is fit for a particular purpose and suitable
for user's method of use or application. Given the variety of
factors that can affect the use and application of a 3M product,
some of which are uniquely within the user's knowledge and control,
it is essential that the user evaluate the 3M product to determine
whether it is fit for a particular purpose and suitable for user's
method of use or application.
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