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Alkylphenolic Novolac Dispersion PageAlkylphenolic Novolac Dispersion MSDS
Permission to post given.
Author:Brandon Adams:
More than 12% of Population Reports
Extreme Sensitivity to Low Levels of Common Chemicals
Study Published Today in Environmental Health Perspectives Finds 1.8% of Population Loses Job as Result [RESEARCH TRIANGLE PARK, NC] Approximately 12.6% of the population suffers from multiple chemical sensitivity (MCS), a condition in which they experience reactions from exposure to low concentrations of common chemicals, according to a study published today in the September issue of the peer-reviewed journal Environmental Health Perspectives (EHP). Of those reporting such hypersensitivity, 13.5% (or 1.8% of the entire sample) reported losing their jobs because of it. Extrapolated to a U.S. population of 290 million, today’s study means as many as 36.5 million Americans are suffering from MCS, and more than 5.2 million may lose jobs as a result. MCS is a condition in which individuals have an acute hypersensitivity to the chemicals in everyday substances, including household cleaning agents, pesticides, fresh paint, new carpeting, building materials, newsprint, perfume, and numerous other petrochemical-based products. Individuals with MCS may experience headaches, burning eyes, asthma symptoms, stomach distress/nausea, dizziness, loss of mental concentration, and muscle pain. Some individuals also suffer fever or even loss of consciousness. Participants in today’s study, all residents of metropolitan Atlanta, were surveyed at random. Those who reported MCS were later interviewed in more detail to understand how the syndrome affects their daily lives. “MCS can produce a wide range of symptoms, and individuals with hypersensitivity can encounter great difficulty functioning in normal working and living environments,” the study authors write. MCS is often triggered, or initiated, by an acute one-time exposure to a specific toxic agent, or chronic exposure to one or more toxic substances, even at low levels. After initiation, a wider range of substances can cause subsequent reactions. A second study in the same issue of EHP discusses how MCS patients responded to various treatments. Patients responded best to having a relatively chemical-free living space, avoiding chemical exposures, and prayer. Certain treatments, including use of common antidepressants, were rated more likely to harm than help. Commenting on the study, Dr. Jim Burkhart, science editor for EHP, says, “There are clearly large numbers of people suffering from MCS. At one point, people theorized that this condition might have a psychological basis, but this study also indicates that very few patients had any mental illness prior to MCS. Unfortunately, over 37% reported emotional problems after their physical symptoms emerged. This is a significant public health issue.” The prevalence study was conducted by Stanley M. Caress of the State University of West Georgia and Anne C. Steinemann of the Georgia Institute of Technology. The study on treatment efficacy was conducted by Pamela Reed Gibson, Amy Nicole-Marie Elms, and Lisa Ann Ruding of James Madison University. EHP is the journal of the National Institute of Environmental Health Sciences, part of the U.S. Department of Health and Human Services. More information is available online at http://www.ehponline.org/. * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * M S D S * * * * Canadian Centre for Occupational Health and Safety * * * * * * * * * * * * * * * * * * * * * (August, 2002) *
*** IDENTIFICATION ***
MSDS RECORD NUMBER
: 3148221
PRODUCT NAME(S)
: ALKYLPHENOLIC NOVOLAC DISPERSION
PRODUCT IDENTIFICATION : MSDS Number 5990
DATE OF MSDS
: 2001-09-17
CURRENCY NOTE
: This MSDS was provided to CCOHS in electronic
form on 2002-02-14
*** MANUFACTURER INFORMATION ***
MANUFACTURER
: Schenectady International, Inc
ADDRESS
: Post Office Box 1046
Schenectady New York U.S.A. 12301 Telephone: 518-887-2400 (General Assistance) EMERGENCY TELEPHONE NO. : 800-424-9300 (CHEMTREC, in USA, 24 Hour Emergency Assistance) 703-527-3887 (International, Call Collect, 24 Hour Emergency Assistance)
*** MATERIAL SAFETY DATA ***
1 CHEMICAL PRODUCT & COMPANY
IDENTIFICATION
ALKYLPHENOLIC NOVOLAC DISPERSION MSDS Number 5990 Issued On 09/17/01 Schenectady International, Inc. P.O. Box 1046 Schenectady , NY12301 Telephone Numbers - 24 Hour Emergency Assistance In USA -- 1-(800)-424-9300 CHEMTREC International (703)-527-3887] [Call Collect] Telephone Numbers - General Assistance General 518-887-2400 NAERG 171 TSCA Status This material is on the TSCA inventory list. Chemical Name / ALKYLPHENOL NOVOLAC RESIN DISPERSION Class CAS Number N/A Synonym(s) WHMIS D2B Classifications HAZARD RATINGS HMIS NFPA Health 1 1 Reactivity 1 1 Flammability 0 0 PPE B Product Use Chemical intermediate This information is considered to represent confidential business information to SII Trade Secret 2 COMPOSITION / INFORMATION ON INGREDIENTS Ingredient Name CAS Weight Trade OSHA Capable Number Range Secret Hazardous of Release ------------------------------------------------------------------- PHENOLIC RESIN N/A 55 - 60 % WATER 7732-18-5 40 - 45 % n ZINC 7440-66-6 1.5 - 3 % y y * ------------------------------------------------------------------- * [NOTE: An * in the Capable of Release field indicates the substance(s) so marked represent either: processing by/co-products and/or residuals. Such may be capable of being released during storage, handling, and/or processing but should not represent a physical, or health, hazard during normal operations. The user of this material has the responsibility to provide a safe work place and, as necessary via job-task analysis: develop appropriate work practices, assign personal protective equipment, and provide instructional programs.] *[NOTE: An * in a HMIS field indicates this material may potentially involve certain chronic health issues such as cancer.]
This material may also
be applicable to the SARA 311/312 regulations. Thus, it may require you to file appropriate governmental reports if the total amount of this material, or any of the listed constituents, in your possession ever exceeds the regulations' threshold values. 3 HAZARDS IDENTIFICATION Hazard Statements ANSI signal word for this material is: CAUTION
Per SARA 312
regulations this material represents the following
health hazard(s): acute Emergency Overview To work safely with this material: keep away from heat and ignition sources avoid contact with eyes, skin, or clothing avoid breathing material's vapors, dust, or fumes keep container closed use with adequate ventilation -- do not enter any confined spaces without first verifying air quality wash thoroughly after handling Risks Health Cautions may cause skin irritation may cause eye irritation may affect mucous membranes may cause gastrointestinal disturbances may affect the respiratory system Potential Concerns -- Materials that are Capable of Release The potential hazards of the substance(s) marked as capable of release are: [alphabetically]
ZINC
HEALTH
WARNINGS:
lung irritant
HEALTH
CAUTIONS:
may cause eye irritation may cause skin irritation may affect mucous membranes
4 FIRST AID MEASURES
Skin Immediately take off all contaminated clothing. For skin contact, flush with large amounts of water. If any adverse effects persist, get medical attention. These symptoms may result from an emergency or an unexpected acute overexposure: irritation Eyes In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. These symptoms may result from an emergency or an unexpected acute overexposure: irritation Inhalation Move person to non-contaminated air. If not breathing, give artificial respiration, preferably mouth-to-mouth. If breathing is difficult, give oxygen. Seek medical attention. These symptoms may result from an emergency or an unexpected acute overexposure: irritation -- respiratory tract Ingestion If the material is swallowed, get immediate medical attention or advice. Never give anything by mouth to a victim who is unconscious or is having convulsions. If patient has a good gag reflex, you can consider giving several ounces of water for dilution. These symptoms may result from an emergency or an acute overexposure: gastritis Cardiovascular These symptoms may result from an emergency or an unexpected acute overexposure: arrhythmia Central Nervous System Monitor for shock; anticipate seizures and treat accordingly. Notes to Physician Provide general supportive measures and treat symptomatically. A
specific
antidote is not known. Some of the symptoms presented
could become life threatening as a result of an emergency or an unexpected acute overexposure. 5 FIRE FIGHTING MEASURES Hazardous Combustion Products Irritating and toxic gases or fumes may be released during a fire. Decomposition of this product may yield metallic oxides.
Sensitivity to Static Discharge
Material can accumulate static charges from material handling management. Bond and ground as appropriate. For additional recommendations, consult National Fire Protection Association [NFPA] bulletin entitled "Static Electricity". All five gallon pails and larger metal containers including tank cars and tank trucks should be grounded and/or bonded when material is transferred. Extinguishing Media Dry chemical, foam, carbon dioxide, water fog. Fire Fighting Equipment / Instructions Exclude air; treat like a gasoline or oil fire. Wear full protective clothing, including helmet, self-contained positive pressure or pressure demand breathing apparatus, protective clothing and face mask. General Fire Hazards This product is an aqueous mixture which will not burn. If evaporated to dryness, the solid residue may pose a slight fire hazard. Flash Point >200 F [>93 C] Tag Closed Cup Substance Name % LEL % UEL -------------------------------------------------------------- ALKYLPHENOLIC NOVOLAC DISPERSION NA NA -------------------------------------------------------------- 6 ACCIDENTAL RELEASE, SPILL, LEAK PROCEDURES Clean-Up Procedures Ventilate the contaminated area. Eliminate ignition sources including sources of electrical, static or frictional sparks. Contain, absorb or, for solids, vacuum or sweep up, material and place in container(s) applicable for ultimate transportation or disposal. Thoroughly clean the release area with a suitable agent and collect any cleaning, rinsing media(s) for proper reclamation or disposal. Wear appropriate personal protective equipment during cleanup activities. Containment Procedures Stop the flow of material, if this is without risk. Eliminate ignition sources. Ventilate the contaminated area. Contain the spill and prevent the material from obtaining access to any confined spaces, public sewers, or waterways. Evacuation Procedures Follow facility/company's emergency plans. Special Procedures Wear appropriate protective equipment and clothing during clean-up. Determine appropriate course of action for the collected material. Regulations vary. Consult local authorities before disposal. 7 HANDLING & STORAGE Handling Procedures Air should be excluded, if at all possible, when closing containers. As with all chemicals, good industrial hygiene practices should be followed when handling this material. When
the container(s)
is empty it may retain product residue including
vapors which could accumulate. Therefore, do not cut, drill, grind, or weld empty containers. Additionally, do not conduct such activity(ies) near full, partially full, or empty product containers without appropriate workplace safety authorization(s) or permit(s). Storage Procedures Protect container from physical abuse. Keep the container tightly closed. Store in a cool, dry, well-ventilated storage area. Protect from freezing. Keep separate from incompatibles. Bond and ground containers when transferring material. Empty product containers may contain product residue. Do not reuse empty containers. 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering Controls Ventilation should be sufficient to effectively remove, and prevent buildup of, any vapors, dusts, or fumes that may be generated during handling or thermal processing. Personal Protective Equipment: Eyes/Face Wear safety glasses with side shields; chemical goggles (if splashing is possible). Wear a face shield if a potentially severe splash hazard exists. Eye protection should be selected by, and used under the direction of, a trained health and safety professional following the requirements found in: OSHA's eye and face protection regulations [29 CFR 1910.133]; or, European Standard EN166. Personal Protective Equipment: Skin Use appropriate hand protection. Wear impervious gloves for prolonged contact. Personal Protective Equipment: Respiratory Prolonged exposure to this material at elevated temperatures may release some volatile organics which may cause nasal or respiratory irritation. Maintain material's vapors, fumes, or particulate ambient levels below any levels of concern including, when appropriate, for solids, considering the material as a particulate not otherwise classified -- nuisance dust -- using a generic dust concentration value of 10 mg/m3. Respirators should be selected by, and used under the direction of, a trained health and safety professional following requirements in: OSHA's respirator standard (29 CFR 1910.134); ANSI's standard (Z88.2-1992); or the European standard [EN 149]. Personal Protective Equipment: General Use good industrial hygiene practices in handling this material. Exposure Guidelines All PPE use is to be determined by a qualified person. 9 PHYSICAL & CHEMICAL PROPERTIES General Milky, white-colored aqueous dispersion. Specific Gravity 1.066 Vapor Pressure N/A Evaporation Rate < Ether Vapor Density > Air Solubility in Water Soluble [>25%] pH Value [4.9] 10 STABILITY & REACTIVITY Conditions to Avoid Do not freeze. Exposing a liquid dispersion to air for extended
periods may
cause coalescence.
Hazardous Decomposition Upon decomposition this product emits carbon monoxide, carbon dioxide, and/or low molecular weight hydrocarbons. Decomposition of this product may yield metallic oxides. Hazardous Polymerization Will not occur under normal conditions. Chemical Stability Stable under normal conditions. Incompatibility This material may react with: strong oxidizing agents
ZINC may react
with: amines; cadmium; carbon dioxide; chlorates;
chlorides; chlorinated hydrocarbons; fluorine; strong acids; strong alkalies; strong bases; sulfur; water [including moist air].
WATER: On
contact with acids, or bases, an exothermic reaction
may occur emitting steam, heat and toxic fumes. 11 TOXICOLOGICAL INFORMATION Routes of Entry inhalation ingestion eye contact skin contact Organs Effected respiratory system Acute Ingestion Oral LD50 WATER 7732-18-5 Oral LD50 [rat]: >90 mL/kg 12 ECOLOGICAL INFORMATION Ecotoxicity WATER WATER does not represent an aquatic toxicity risk.
Environmental Fate
No data available for this product. 13 DISPOSAL CONSIDERATIONS Disposal Instructions All wastes must be handled in accordance with local, state and federal regulations. CERCLA/SARA - Hazardous Substances and their Reportable Quantities ZINC 7440-66-6 final RQ = 1000 pounds (454 kg) (no reporting of releases of this hazardous substance is required if the diameter of the solid metal released is equal to or exceeds 0.004 inches) 14 TRANSPORT INFORMATION Comments NOTE: The data in this section are provided as a guide for the overall classification of the product. However, transportation classifications may be subject to change as, for example, with changes in package size. Consult shipper requirements under IMO, ICAO (IATA), TDG and 49 CFR to assure regulatory compliance.
Additionally,
please address any questions you have concerning
the cleaning of containers, or vessels, to the Transportation & Regulatory Affairs Specialist with Schenectady International, Inc., at (518)-370-4200. Remember that the reuse, treatment, or disposal, of any related residuals or wastes must be in
accordance with
all federal, state, and local environmental
regulations. GROUND TRANSPORTATION BULK Shipping Name Resin, coal tar or petroleum, not DOT hazardous Hazard Class Identification Number Packing Group GROUND TRANSPORTATION NON-BULK Shipping Name Resin, coal tar or petroleum, not DOT hazardous Hazard Class Identification Number Packing Group SURFACE TRANSPORTATION (HIGHWAY/RAIL) BULK-- TANK TRUCK/TANK CAR Shipping Name Resin, coal tar or petroleum, not DOT hazardous DRUM(s)/BAG(s) Shipping Name Resin, coal tar or petroleum, not DOT hazardous INTERMEDIATE BULK CONTAINER Shipping Name Resin, coal tar or petroleum, not DOT hazardous PAIL(s)/CAN(s) Shipping Name Resin, coal tar or petroleum, not DOT hazardous IMDG CODE (WATER) DRUM(s)/BAG(s) Shipping Name Resin, coal tar or petroleum, non-dangerous INTERMEDIATE BULK CONTAINER Shipping Name Resin, coal tar or petroleum, non-dangerous PAIL(s)/CAN(s) Shipping Name Resin, coal tar or petroleum, non-dangerous ICAO/IATA (AIR) DRUM(s)/BAG(s) Shipping Name Resin, coal tar or petroleum, not restricted PAIL(s)/CAN(s) Shipping Name Resin, coal tar or petroleum, not restricted 15 REGULATORY INFORMATION U.S. Federal Regulations Superfund Amendments & Reauthorization Act of 1986 CERCLA/SARA - Section 313 - Emission Reporting ZINC 7440-66-6 form R reporting required for 1.0% de minimus concentration (only fume or dust) State Regulations California - Directors List of Hazardous Substances (8 CCR 339) ZINC 7440-66-6 [present] Florida Substance List ZINC 7440-66-6 [present] Massachusetts Right To Know List ZINC 7440-66-6 [present] Michigan Critical Materials List ZINC 7440-66-6 Class 02-7; all compounds (inorganic and organic) are to be reported New Jersey - Department of Health RTK List
ZINC
7440-66-6 sn 2021 (dust and fume)
New Jersey - Environmental Hazardous Substances List ZINC 7440-66-6 (fume or dust), sn 2021 Pennsylvania Right to Know List ZINC 7440-66-6 environmental hazard (any compound of this substance is also an environmental hazard) Rhode Island Hazardous Substance List ZINC 7440-66-6 Flammable International Regulations Canada - NPRI (National Pollutant Release Inventory) for 1999 ZINC 7440-66-6 [present] (as fume or dust) Inventory - Canada - Domestic Substances List WATER 7732-18-5 H2O ZINC 7440-66-6 Zn Inventory - European Inventory of Existing Commercial Chemical Substances WATER 7732-18-5 231-791-2; H2O ZINC 7440-66-6 231-175-3; Zn Canadian WHMIS Classifications WHMIS This material is not hazardous per these regulations. D2B: Chronic Lethality -- Toxic may cause eye irritation may cause skin irritation may affect mucous membranes may cause gastrointestinal disturbances may affect the respiratory system 16 OTHER INFORMATION Disclaimer The health and safety information is that available to SII/SCL as of the date published and SII/SCL makes no representation of the information's completeness or accuracy. Any data provided is based on either: reference sources, testing performed on a representative sample(s), or professional judgement. The physical data should not be construed as either representing specifications or a guaranteed analysis. This material has been classified in accordance with the hazard criteria of the Controlled Products Regulation and the MSDS contains information required by Controlled Products Regulation. SII/SCL provides its MSDS in several languages using English as the primary language. While SII/SCL uses reasonable efforts to provide accurate translations, SII/SCL assumes no liability, or responsibility, for errors, omissions or ambiguities in any translations. SII/SCL expects those persons who receive this MSDS to exercise their independent professional judgement, or consult with a competent health/safety professional, to determine how to utilize this material safely. This includes, but is not exclusive to, the material's appropriateness for a specific use, the type of personal protection equipment necessary, and the use of engineering controls. In no event is SII/SCL liable for any damages whatsoever arising out of your use of this material based upon information obtained from this MSDS including: direct, indirect, incidental, consequential or punitive claims or damages. Completed On 9/17/01 Replaces Sheet 9/17/01 14:00:34 Dated 13:50:01 Completed By HGW
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©2002 Canadian Centre for Occupational Health &
Safety
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